3.29: all damage from Critical Strikes can apply Lightning Ailments during effect, +5% max Lightning Resistance. Shock from any damage type.
lightning
crit
ailment
Ascendancies that suit it
Assassin — A critical-strike specialist who lives and dies by the poison and the killing blow. 3.29's Mystical Infusion drags it back toward pure spellcasting.
Elementalist — Splits elemental damage across golems and ailments until the battlefield is unrecognizable.